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Catalysts which allow the polymerization of ethylene to obtain polymer products of a medium or high molecular weight are metal halides, usually in the form of a reaction product of a transition metal compound having at least one halogen atom and a trialkylaluminum; metal alkyls; and combinations of these; see European patent application EP-A,, the catalyst being generally obtained by contacting a Group 4 metal selected from titanium, zirconium and hafnium, with a trialkylaluminum and an excess of methylic halide generally a methylic halogenide optionally supported by one or more solvents.
Other catalysts, which allow the polymerization of ethylene to obtain polymers of high molecular weight, are metallocenes complexed with aluminoxanes, also known as metallocene-aluminoxane catalysts. In European patent application EP-A-0,,, a process for the polymerization of ethylene in the presence of a metallocene-aluminoxane catalyst is described.
This catalyst, which is obtained by introducing a metallocene compound onto a support having at least one acidic hetero-atom, allows obtaining polyethylene with good properties of thermal and mechanical stress resistance and particularly a good resistance to ageing at high temperature. The catalysts of the art have, however, serious drawbacks. In particular, they suffer from a lack of stability polymerization activity , stability of the catalyst components, especially the metallocene, and a lack of resistance to polar impurities.
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